Synthesis of a Sodium-Ion Cathode Material Na3Fe2(SO4)3F with the Help of Fluorine Element

Autor: Wei, Wei, Ye, Tao, Xiao, Zunqiu, Xiang, Kejia, Wang, Huaying, Zhang, Zhongtai, Wang, Shitong, Tang, Zilong
Zdroj: ACS Applied Materials & Interfaces; September 2024, Vol. 16 Issue: 37 p49362-49370, 9p
Abstrakt: The development of cathode materials has always been one of the most crucial areas of research in the field of sodium-ion batteries. Sulfate-based polyanionic materials, known for their high working voltage characteristics, have received widespread attention. In this work, a fluoro-sulfate sodium-ion battery cathode material, Na3Fe2(SO4)3F modified with carbon nanotubes, was developed using a low-temperature solid-state annealing method. This Na3Fe2(SO4)3F cathode exhibits an exceptionally high voltage of 3.77 V, excellent discharge capacity (102 mAh/g at 0.1C), and good rate capability. This material broadens the research directions for cathode materials and holds promise as a foundation for the further development of high-performance sodium-ion batteries.
Databáze: Supplemental Index