| Autor: |
Hedrich, Carina, James, Nithin T., Maragno, Laura G., de Lima, Valéria, González, Sergio Yesid Gómez, Blick, Robert H., Zierold, Robert, Furlan, Kaline P. |
| Zdroj: |
ACS Applied Materials & Interfaces; September 2024, Vol. 16 Issue: 36 p46964-46974, 11p |
| Abstrakt: |
The use of solar energy for photocatalysis holds great potential for sustainable pollution reduction. Titanium dioxide (TiO2) is a benchmark material, effective under ultraviolet light but limited in visible light utilization, restricting its application in solar-driven photocatalysis. Previous studies have shown that semiconductor heterojunctions and nanostructuring can broaden the TiO2’s photocatalytic spectral range. Semiconductor heterojunctions are interfaces formed between two different semiconductor materials that can be engineered. Especially, type II heterojunctions facilitate charge separation, and they can be obtained by combining TiO2with, for example, iron(III) oxide (Fe2O3). Nanostructuring in the form of 3D inverse opals (IOs) demonstrated increased TiO2light absorption efficiency of the material, by tailoring light-matter interactions through their photonic crystal structure and specifically their photonic stopband, which can give rise to a slow photon effect. Such effect is hypothesized to enhance the generation of free charges. This work focuses on the above-described effects simultaneously, through the synthesis of TiO2–Fe2O3IOs via multilayer atomic layer deposition (ALD) and the characterization of their photocatalytic activities. Our results reveal that the complete functionalization of TiO2IOs with Fe2O3increases the photocatalytic activity through the slow photon effect and semiconductor heterojunction formation. We systematically explore the influence of Fe2O3thickness on photocatalytic performance, and a maximum photocatalytic rate constant of 1.38 ± 0.09 h–1is observed for a 252 nm template TiO2–Fe2O3bilayer IO consisting of 16 nm TiO2and 2 nm Fe2O3. Further tailoring the performance by overcoating with additional TiO2layers enhances photoinduced crystallization and tunes photocatalytic properties. These findings highlight the potential of TiO2–Fe2O3IOs for efficient water pollutant removal and the importance of precise nanostructuring and heterojunction engineering in advancing photocatalytic technologies. |
| Databáze: |
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