| Autor: |
Ning, Jingran, Du, Baoyang, Cao, Shilong, Liu, Xia, Kong, Duanyang |
| Zdroj: |
Organic Letters; 20240101, Issue: Preprints |
| Abstrakt: |
The integration of umpolung and carbon isotope exchange for accessing isotopically labeled α-keto acids through photoredox catalysis is elucidated. This process involves the carbonyl umpolung of C(sp2)-α-keto acids to yield C(sp3)-α-thioketal acids, followed by the carbon isotope exchange of C(sp3)-α-thioketal acids, and ultimately, deprotection to generate carbon-labeled α-keto acids. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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