HydroaminationHeck reaction sequence for a highly regioselective one-pot synthesis of indoles using 2-chloroanilineElectronic supplementary information (ESI) available: details of the synthesis of compounds in Table 1 and 2including analytical and spectroscopic data for new compounds. See http://www.rsc.org/suppdata/cc/b4/b411571f/
| Autor: | Ackermann, Lutz, Kaspar, Ludwig T., Gschrei, Christian J. |
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| Zdroj: | Chemical Communications; 2004, Vol. 2004 Issue: 24 p2824-2825, 2p |
| Abstrakt: | A one-pot indole synthesis consisting of a highly regioselective TiCl4-catalyzed hydroamination and a 5-endoHeck cyclization starting from 2-chloroaniline is described, using an in-situgenerated, sterically hindered imidazol-2-ylidene palladium complex. |
| Databáze: | Supplemental Index |
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