Palladium nanoparticles obtained from palladium salts and tributylamine in molten tetrabutylammonium bromide: their use for hydrogenolysis-free hydrogenation of olefinsElectronic supplementary information (ESI) available: electron diffraction pattern of PdCl,N. See http://www.rsc.org/suppdata/nj/b4/b409604e/

Autor: Le Bras, Jean, Mukherjee, Deb Kumar, González, Sara, Tristany, Mar, Ganchegui, Benjamin, Moreno-Mañas, Marcial, Pleixats, Roser, Hénin, Françoise, Muzart, Jacques
Zdroj: New Journal of Chemistry; 2004, Vol. 28 Issue: 12 p1550-1553, 4p
Abstrakt: Carbon-carbon double bonds have been selectively hydrogenated at room temperature in the presence of benzyloxy groups using an atmospheric pressure of hydrogen, toluene or [bmim]PF6as the solvent and palladium nanoparticles stabilized with tetrabutylammonium bromide. The system [bmim]PF6/palladium nanoparticles can be recycled without noticeable decrease of activity.
Databáze: Supplemental Index