Validation of Lanthanide Chiral Shift Reagents for Determination of Absolute Configuration:  Total Synthesis of Glisoprenin A

Autor: Adams, C. M., Ghosh, I., Kishi, Y.
Zdroj: Organic Letters; December 2004, Vol. 6 Issue: 25 p4723-4726, 4p
Abstrakt: The complete stereostructure of the natural product (+)-glisoprenin A had been predicted via a novel application of chiral lanthanide shift reagents. Confirmation of the predicted stereostructure of (+)-glisoprenin A and validation of the chiral lanthanide shift approach have now been achieved through total synthesis.
Databáze: Supplemental Index