Asymmetric Synthesis of Deoxypolypropionate Units via Stereoselective Hydrogenation of Optically Active Cycloheptatriene

Autor:	Sugimura, T., Sato, Y., Im, C. Y., Okuyama, T.
Zdroj:	Organic Letters; November 2004, Vol. 6 Issue: 24 p4439-4442, 4p
Abstrakt:	Optically active polypropionate units were synthesized in 9−11 steps from 3,5-dimethylphenol. The sequence consists of the Büchner reaction controlled by a chiral 2,4-pentanediol tether and diastereoselective hydrogenation over Raney nickel.
Databáze:	Supplemental Index
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