Hydrogenolysis of isosorbide to diols and triols over a heterogeneous SiO2-supported Rh catalystElectronic supplementary information (ESI) available. See DOI: https://doi.org/10.1039/d4cy00266k

Autor: Chen, Pengru, Onodera, Wataru, Akatsuka, Masato, Kita, Yusuke, Tamura, Masazumi
Zdroj: Catalysis Science & Technology; 2024, Vol. 14 Issue: 11 p3001-3006, 6p
Abstrakt: Silica-supported Rh (Rh/SiO2) was an effective and reusable heterogeneous catalyst for the hydrogenolysis of isosorbide, providing diols and triols in 58% total yield. The yield was higher than those obtained by hydrogenolysis of glucose and sorbitol, confirming the high potential of isosorbide as a biomass-derived intermediate for the synthesis of polyols.
Databáze: Supplemental Index