Surface‐Initiated Polymerization on Self‐Assembled Monolayers: Effect of Reaction Conditions

Autor: Schmelmer, Ursula, Paul, Anne, Küller, Alexander, Jordan, Rainer, Gölzhäuser, Armin, Grunze, Michael, Ulman, Abraham
Zdroj: Macromolecular Symposia; October 2004, Vol. 217 Issue: 1 p223-230, 8p
Abstrakt: Self‐assembled monolayers of 4′‐nitro‐4‐mercaptobiphenyl were modified by electron beam irradiation and diazotization to create a surface‐bond asymmetric azo initiator for the surface‐initiated polymerization (SIP). The effect of different reaction conditions upon the thermally and photochemical initiated SIP was investigated.
Databáze: Supplemental Index