Autor: |
Hulin, B., Newton, L. S., Cabral, S., Walker, A. J., Bordner, J. |
Zdroj: |
Organic Letters; November 2004, Vol. 6 Issue: 23 p4343-4345, 3p |
Abstrakt: |
1,5-Cyclooctadiene can be stereoselectively transformed into a substituted bicyclo[3.3.0]octane ring system under palladium catalysis with concomitant formation of three carbon−carbon bonds. Reaction with an aryl iodide or triflate and malonate gives an exo-endo product, while the reaction with a malonate in the presence of oxygen affords a bis-endo adduct. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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