Hypervalent Iodine-Mediated Vicinal Syn Diazidation:  Application to the Total Synthesis of (±)-Dibromophakellstatin

Autor: Chung, R., Yu, E., Incarvito, C. D., Austin, D. J.
Zdroj: Organic Letters; October 2004, Vol. 6 Issue: 22 p3881-3884, 4p
Abstrakt: The total synthesis of (±)-dibromophakellstatin is described. The molecule is constructed from a key syn-diazide, formed by a hypervalent iodine-mediated diazidation of a dihydrodipyrrolopyrazinone ring structure.
Databáze: Supplemental Index
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