Synthesis and Crystal Structures of [CuCl2(μ-NSPh3)]2and [CuCl2(Ph3SN)2]: Novel Copper Complexes Bearing Organic λ6-Sulfanenitrile as Ligand

Autor: Yoshimura, Toshiaki, Fujii, Takayoshi, Dai, Huagang
Zdroj: Chemistry Letters; October 2002, Vol. 31 Issue: 10 p1000-1001, 2p
Abstrakt: Dinuclear complex [CuCl2(μ-NSPh3)]2(2) and mononuclear complex [CuCl2(Ph3SN)2] (3) were obtained concurrently by a reaction of CuCl2with triphenyl-λ6-sulfanenitrile (1) in acetonitrile. They were characterized by elemental analysis, IR and NMR spectroscopy, and their molecular structures were determined by X-ray crystallographic analysis.
Databáze: Supplemental Index