| Autor: |
Zuo, Jianyi, Feng, Qiuyuan, Du, Hong |
| Zdroj: |
Inorganic Chemistry; January 2024, Vol. 63 Issue: 1 p272-279, 8p |
| Abstrakt: |
A new borophosphate, K2RbB8PO16(KRBPO) was synthesized. It exhibits a bilayer structure consisting of two B–O layers with an 18-membered ring (18-MR) joined by [PO4], which is composed of the π-conjugated group [BO3] and non-π-conjugated groups [BO4] and [PO4]. The UV–vis–NIR diffuse reflectance spectroscopy shows that the cutoff edge is less than 200 nm. The calculation indicates that KRBPO exhibits moderate birefringence of 0.057@1064 nm, and the source of birefringence is mainly from the [BO3] groups. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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