A CONVENIENT SYNTHESIS OF BENZYLMETHYLCHLOROSILANES BY THE PALLADIUM-CATALYZED DECHLORINATIVE SILYLATION OF BENZYLIC CHLORIDES WITH METHYLCHLORODISILANES
| Autor: | Matsumoto, Hideyuki, Kasahara, Miyuki, Matsubara, Ikuya, Takahashi, Masatoshi, Nakano, Taichi, Nagai, Yoichiro |
|---|---|
| Zdroj: | Chemistry Letters; March 1982, Vol. 11 Issue: 3 p399-400, 2p |
| Abstrakt: | Benzylmethylchlorosilanes were prepared in high yields by the dechlorinative silylation of benzylic chlorides with methylchlorodisilanes MenSi2Cl6−n(n = 2,3, and 4) in the presence of a catalytic amount of Pd(PPh3)4. |
| Databáze: | Supplemental Index |
| Externí odkaz: |
|