NMR STUDY OF HIGH PRESSURE EFFECTS ON MOLECULAR CONFORMATIONS OF 2,11-DITHIA[3.3.1]PARACYCLOPHANE AND 2,11-DITHIA[3.3.2]PARACYCLOPHANE

Autor: Imashiro, Fumio, Saika, A, Yamada, Hiroaki, Sera, Akira
Zdroj: Chemistry Letters; February 1981, Vol. 10 Issue: 2 p247-250, 4p
Abstrakt: A high-pressure high-resolution NMR study for 2,11-dithiaI3.3.n]paracyclophanes (n=1,2) revealed that the Hxprotons of ring A shift notably to high field, whereas the Ha,bprotons of ring B move to low field. Reduction of the partial volumes under high pressure, being effected by changes in the dihedral angles, is responsible for the chemical shift changes.
Databáze: Supplemental Index