SYNTHESIS AND THE MOLECULAR STRUCTURE OF ACETATOTRICHLORO(TRIPHENYLPHOSPHINE OXIDE)TIN(IV)

Autor: Masaki, Mitsuo, Matsunami, Satoshi, Okimoto, Kiyomi, Ueda, Hideo
Zdroj: Chemistry Letters; January 1978, Vol. 7 Issue: 1 p119-122, 4p
Abstrakt: Acetatotrichloro(triphenylphosphine oxide)tin(IV) was synthesized by the reaction of stannic chloride, acetic acid and triphenylphosphine oxide or by the reaction of dichlorotin(IV) diacetate with tetrachlorobis(triphenylphosphine oxide)tin(IV). The structure of the complex was determined by the X-ray method. The molecule is monomeric and tin atom is six-coordinated.
Databáze: Supplemental Index