HOMOALLYLIC REARRANGEMENTS OF 4-SPIRO[2.4]HEPTYL RADICAL AND 4-SPIRO[2.5]OCTYL RADICAL
| Autor: | Suzuki, Mikio, Murahashi, Shun-Ichi, Sonoda, Akio, Moritani, Ichiro |
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| Zdroj: | Chemistry Letters; March 1974, Vol. 3 Issue: 3 p267-270, 4p |
| Abstrakt: | Irradiation of azobis(4-spiro[2.4]heptane) and azobis(4-spiro[2.5]octane) afforded homoallylically rearranged products via the corresponding titled radicals, in which the rigid geometry locks the cyclopropylcarbinyl radical in the stable bisected conformation. |
| Databáze: | Supplemental Index |
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