PHOTOINDUCED REACTIONS. LXV. PHOTOSENSITIZED OXYGENATION OF 2-METHYLINDOLES

Autor: Saito, Isao, Imuta, Mitsuru, Matsuura, Teruo
Zdroj: Chemistry Letters; December 1972, Vol. 1 Issue: 12 p1173-1176, 4p
Abstrakt: Photosensitized oxygenation of 2-methylindole and 1,2-dimethylindole gave 2-methyl-2-[3-(2-methylindolyl)]indoxyl and its N,N′-dimethyl derivative, respectively, which were possibly formed through a hydroperoxide intermediate, whereas 1,2,3-trimethylindole underwent oxidative 2,3-cleavage to give o-(N-acetyl-N-methyl)aminoacetophenone.
Databáze: Supplemental Index