Prediction of Structural Effects of Trialkylsilyl Groups on Reactivity toward Nucleophilic Displacement at Silicon
| Autor: | Shimizu, Nobujiro, Takesue, Naohide, Yasuhara, Sigefumi, Inazu, Takahiko |
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| Zdroj: | Chemistry Letters; October 1993, Vol. 22 Issue: 10 p1807-1810, 4p |
| Abstrakt: | A quantitative method of predicting reactivities of trialkylsilyl groups relative to Me3Si toward nucleophilic displacement at silicon has been established on the basis of statistical analyses of the rates of solvolysis for a comprehensive series of chlorosilanes in aqueous dioxane. |
| Databáze: | Supplemental Index |
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