Compositional Variation of Ionizable Crown Ether-Alkali Metal Ion Complexes in the Solvent Extraction Using Several Extraction Solvents

Autor: Sakamoto, Hidefumi, Goto, Hiroki, Doi, Kunio, Otomo, Makoto
Zdroj: Chemistry Letters; August 1992, Vol. 21 Issue: 8 p1535-1538, 4p
Abstrakt: Novel benzo-15-crown-5 and 18-crown-6 derivatives bearing an ionizable hydrazone group were synthesized and complex formation equilibria of the compounds with alkali metal ions in solvent extraction were evaluated spectrophotometrically. Formation of 2:2 complexes of the crown ethers with metal ions was observed using chloroform as an extraction solvent.
Databáze: Supplemental Index