Structural Characterization of the Transition-metal Imido Complex Coordinated in a Bidentate Fashion. Preparation and the Molecular Structure of Seven-Coordinate Hydrido(succinimido-N,O)bis[1,2-bis(dipehnylphosphino)ethane]molybdenum(II)

Autor: Kurishima, Susumu, Ito, Takashi
Zdroj: Chemistry Letters; August 1990, Vol. 19 Issue: 8 p1299-1302, 4p
Abstrakt: The photoreaction of [MoH4(dppe)2] with succinimide gave [MoH(succinimido-N,O)(dppe)2], which was characterized spectroscopically as well as X-ray crystallographically to have the imido ligand coordinated to the metal bidentately vianitrogen and oxygen atoms constructing four membered metallacycle.
Databáze: Supplemental Index