Structural Characterization of the Transition-metal Imido Complex Coordinated in a Bidentate Fashion. Preparation and the Molecular Structure of Seven-Coordinate Hydrido(succinimido-N,O)bis[1,2-bis(dipehnylphosphino)ethane]molybdenum(II)
Autor: | Kurishima, Susumu, Ito, Takashi |
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Zdroj: | Chemistry Letters; August 1990, Vol. 19 Issue: 8 p1299-1302, 4p |
Abstrakt: | The photoreaction of [MoH4(dppe)2] with succinimide gave [MoH(succinimido-N,O)(dppe)2], which was characterized spectroscopically as well as X-ray crystallographically to have the imido ligand coordinated to the metal bidentately vianitrogen and oxygen atoms constructing four membered metallacycle. |
Databáze: | Supplemental Index |
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