Effects of Si–Si σ-Bonds on Stability of Adjacent Benzylic Cations
| Autor: | Shimizu, Nobujiro, Kinoshita, Chieko, Osajima, Erika, Tsuno, Yuho |
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| Zdroj: | Chemistry Letters; October 1990, Vol. 19 Issue: 10 p1937-1940, 4p |
| Abstrakt: | Solvolytic formation of α-pentamethyldisilanylbenzyl cation is about 7 kcal/mol energetically more favorable than that of α-trimethylsilylbenzyl cation from the corresponding bromides in 97% TFE. |
| Databáze: | Supplemental Index |
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