Syntheses and the Beckmann Fission of Cyclic α-Hydroxyimino Ketones

Autor: Kataoka, Mutsuo, Ohno, Masaji
Zdroj: Bulletin of the Chemical Society of Japan; November 1973, Vol. 46 Issue: 11 p3474-3477, 4p
Abstrakt: A convenient method for the preparation of α-hydroxyimino cycloalkanones has been established by the reaction of cycloalkanones and nitrosyl chloride. ω-Cyanocarboxylic acids or their derivatives were obtained in good yield by the Beckmann rearrangement of these α-hydroxyimino ketones.
Databáze: Supplemental Index