Silver Ion Catalysed Oxidation of Primary Aliphatic Amines by Potassium Peroxydisulfate — A Kinetic Study

Autor: Babu, J Sreekantha, Joshi, Km Veena, Bhattacharya, A K
Zdroj: Bulletin of the Chemical Society of Japan; July 1976, Vol. 49 Issue: 7 p1820-1823, 4p
Abstrakt: A detailed kinetic study of the oxidation of propyl-, isopropyl-, butyl- and isobutylamines by potassium peroxydisulfate in presence of silver ions has been carried out in aqueous medium. The effects of silver ion concentration and various neutral salts have been detected and the variation of the order of reaction with respect to amine had been explained. The activity of Ag+ion has been correlated with the amine structure and probable rate law and the mechanism has been proposed.
Databáze: Supplemental Index