| Autor: |
He, Chuangchuang, Ding, Pingping, Hu, Chuanchuan, Zhang, Xiuyun, Li, Wei, Sun, Shutao |
| Zdroj: |
Chemistry Letters; August 2021, Vol. 50 Issue: 8 p1496-1499, 4p |
| Abstrakt: |
A NaOtBu catalyzed direct 1,6-hydrophosphonylation of d-aryl-d-CF3substituted p-QMs with diarylphosphine oxides has been described. A broad range of different electronic and steric substituted p-QMs and diarylphosphine oxides were well tolerated under the optimized conditions, furnishing a series of quaternary a-trifluoromethyl substituted phosphonates derivatives in high efficiency.A NaOtBu catalyzed direct 1,6-hydrophosphonylation of d-aryl-d-CF3substituted p-QMs with diarylphosphine oxides has been described. A broad range of different electronic and steric substituted p-QMs and diarylphosphine oxides were well tolerated under the optimized conditions, furnishing a series of quaternary a-trifluoromethyl substituted phosphonates derivetives in high efficiency. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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