STRUCTURE AND THERMAL RACEMIZATION OF 1,1,1-TRIS(5-AMINO-2-AZA-PENTYL)ETHANECOBALT(III) COMPLEX
| Autor: | Tomioka, Kanji, Kashihara, Takaki, Sakaguchi, Ushio, Yoneda, Hayami |
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| Zdroj: | Chemistry Letters; July 1984, Vol. 13 Issue: 7 p1047-1050, 4p |
| Abstrakt: | The chiral form of the title complex ion, [Co(stn)]3+, has been found to racemize thermally both in the solid state and in solution, and the racemization rates have been measured. The structure of [Co(stn)]Cl3·3.5H2O has been determined and used to discuss the origin of this facile racemization. |
| Databáze: | Supplemental Index |
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