ASSOCIATION AND REACTIVITY OF AMPHIPHILIC FLAVINS. 8-ALKYL MERCAPTOFLAVINS AND THE CORRESPONDING BIS-FLAVINS IN AQUEOUS SOLUTION

Autor: Yano, Yumihiko, Ohya, Eiichi, Kuwabara, Yoshinori
Zdroj: Chemistry Letters; June 1984, Vol. 13 Issue: 6 p1009-1012, 4p
Abstrakt: It was found that 8-octyl mercaptoflavin forms a dimer in aqueous solution, and the absorption spectrum is quite similar to that of the corresponding bis-flavin linked by -(CH2)3- at 10,10'-positions of the isoalloxazine rings. The association mode and the reactivity for oxidation of N-benzyl-1,4-dihydronicotinamide(BNAH) are discussed.
Databáze: Supplemental Index