THE REACTION OF 2H-THIIN DERIVATIVES WITH PERACID. RING CONTRACTION AND ALKOXYLATION REACTIONS
| Autor: | Ohmura, Haruo, Motoki, Shinichi |
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| Zdroj: | Chemistry Letters; November 1984, Vol. 13 Issue: 11 p1973-1976, 4p |
| Abstrakt: | The cycloaddition reaction of aromatic thioketones (aryl naphthyl thioketones and 2-benzofuryl phenyl thioketone) with 2-chloroacrylonitrile followed by elimination of hydrogen chloride gave some 2H-thiin derivatives. The products reacted with MCPBA and an alcohol to afford ring-contracted product and alkoxylated derivatives. |
| Databáze: | Supplemental Index |
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