| Autor: |
Funakoshi, Masaki, Komiyama, Hiroshi, Inoue, Hakuai |
| Zdroj: |
Chemistry Letters; February 1985, Vol. 14 Issue: 2 p245-248, 4p |
| Abstrakt: |
Ni28Ti72alloy catalyst was found to have a high selectivity for the hydrogenation of acrolein to propionaldehyde. However, both the carbon-carbon double bond and the formyl group were hydrogenated by supported nickel or nickel ultra-fine particles, leading to the simultaneous production of 1-propanol together with propionaldehyde. The retardation of the formyl group hydrogenation by alloying has been suggested to be caused by the electronic effect. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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