CARBON–CARBON BOND FORMATION VIA PHOSPHINE-INITIATED CLEAVAGE OF β-OXOSULFIDES
| Autor: | Ueno, Yoshio, Yadav, L D S, Okawara, Makoto |
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| Zdroj: | Chemistry Letters; June 1983, Vol. 12 Issue: 6 p831-834, 4p |
| Abstrakt: | 2-(Phenacylthio) benzothiazole (1) reacted with aldehyde or ketone in the presence of tri-n-butylphosphine at 80 °C to give α,β-enone and 2-mercaptobenzothiazole in good yield. The reaction scheme for this new type of enolate ion formation via C–S bond cleavage is also described. |
| Databáze: | Supplemental Index |
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