| Autor: |
Okawa, Hisashi, Kanda, Wakako, Kida, Sigeo |
| Zdroj: |
Chemistry Letters; October 1980, Vol. 9 Issue: 10 p1281-1284, 4p |
| Abstrakt: |
Copper(II)–iron(III) binuclear complexes, CuFe(fsaR)Cl·nH2O, with N,N′-bis(3-carboxysalicylidene) alkanediamines (H4fsaR) were prepared and characterized. Cryomagnetic measurements indicated a considerably strong antiferromagnetic spin-exchange interaction operating between the metal ions. The exchange integrals (ca.−50 cm−1) are the largest among the copper(II)–iron(III) complexes so far reported, and hence the complexes mimic the cytochrome oxidase active center. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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