MOLECULAR STRUCTURE OF DINACTIN

Autor: Nawata, Yoshiharu, Hayashi, Toshiaki, Iitaka, Yoichi
Zdroj: Chemistry Letters; March 1980, Vol. 9 Issue: 3 p315-318, 4p
Abstrakt: The molecular conformation of dinactin, one of the homologues of macrotetrolide antibiotics nonactin, was determined by the X-ray diffraction method using a mixed crystal of dinactin and monactin (7:3). The conformation of the 32-membered ring looks a deformed cradle with an asymmetric shape, and can approximately be described as a hybrid of the nonactin and tetranactin type conformations. Dinactin type conformer has the lowest conformation energy among the three.
Databáze: Supplemental Index