PREFERRED CONFORMATIONS OF 9-MONOSUBSTITUTED DERIVATIVES OF 8,9,10,11-TETRAHYDRO-7H-CYCLOOCTA[de]NAPHTHALENE

Autor: Kamada, Toshihiro, Yamamoto, Osamu
Zdroj: Chemistry Letters; January 1980, Vol. 9 Issue: 1 p111-114, 4p
Abstrakt: The conformations of 8,9,10,11-tetrahydro-7H-cycloocta[de]naphthalen-9-ol and its esters have been studied based on the NMR spectra. It was found that these compounds assume solely the equatorial-boat (eb) conformations in solution, the peri rings of which are unusually rigid as compared with the conformations previously reported.
Databáze: Supplemental Index