ORGANORUTHENIUM(II) COMPLEXES PRODUCED BY INSERTION REACTIONS OF SUBSTITUTED OLEFINS INTO A HYDRIDO-RUTHENIUM BOND

Autor: Hiraki, Katsuma, Sasada, Yoko, Kitamura, Tsuneyuki
Zdroj: Chemistry Letters; April 1980, Vol. 9 Issue: 4 p449-452, 4p
Abstrakt: Dimethyl fumarate, 2-vinylpyridine, and acrylonitrile insert into a H–Ru bond of [RuClH(CO)(PPh3)3] (1) to yield new substituted alkylruthenium(II) complexes. Methyl sorbate also reacted with 1to give a new substituted ?3-allylruthenium(II) complex.
Databáze: Supplemental Index