THE CRYSTAL STRUCTURE OF CYCLOOCTA-1,5-DIENE-4-DIPHENYLPHOSPHINO-2-DIPHENYLPHOSPHINOMETHYLPYRROLIDINE(PPM)-RHODIUM(I) PERCHLORATE

Autor: Ohga, Yoko, Iitaka, Yoichi, Achiwa, Kazuo
Zdroj: Chemistry Letters; July 1980, Vol. 9 Issue: 7 p861-864, 4p
Abstrakt: The crystal structure of the title compound which has almost no chiral activity in hydrogenation reaction was determined by X-ray diffraction method. The coordination of the rhodium ion was found to be a trigonal bipyramid, the apices being occupied by a diene group and an imino group of the pyrrolidine ring.
Databáze: Supplemental Index