Novel Copolyamides Containing [60]Fullerene in the Main Chain

Autor: Li, Jing, Yoshizawa, Toshiyuki, Ikuta, Mari, Ozawa, Masaki, Nakahara, Kentaro, Hasegawa, Tetsuya, Kitazawa, Koichi, Hayashi, Minoru, Kinbara, Kazushi, Nohara, Masao, Saigo, Kazuhiko
Zdroj: Chemistry Letters; October 1997, Vol. 26 Issue: 10 p1037-1038, 2p
Abstrakt: Novel copolymers, poly(1,4-oxybisphenylene fullerenobisacetamide-co-1,4-oxybisphenylene isophthalamide)s, which contained [60]fullerene in the main chain, were synthesized by the direct copolycondensation of a mixture of [60]fullerenobisacetic acid and isophthalic acid with 4,4′-diaminodiphenyl ether in the presence of triphenylphosphite and pyridine. Light scattering measurements for the copolymers showed a weight-average molecular weight Mw of about 5-6 × 104. The UV-visible spectra of the copolymers exhibited the characteristics of the parent fullerene derivative. The absorption edge red-shifted from 370 nm for poly(1,4-oxybisphenylene isophthalamide) to about 700 nm for the copolymers.
Databáze: Supplemental Index