The First Stable Aromatic S-Nitrosothiol: Synthesis, Structure and Reactivity

Autor: Itoh, Maiko, Takenaka, Keiko, Okazaki, Renji, Takeda, Nobuhiro, Tokitoh, Norihiro
Zdroj: Chemistry Letters; December 2001, Vol. 30 Issue: 12 p1206-1207, 2p
Abstrakt: The first stable aromatic S-nitrosothiol, S-nitroso-4-t-butyl-2,6-bis[(2,2″, 6,6″-tetramethyl-m-terphenyl-2′-yl)methyl]benzenethiol, was synthesized by the nitrosation of the corresponding thiol and the structure was established by X-ray crystallography. Its oxidation and reactions with some nucleophiles were carried out.
Databáze: Supplemental Index