Structure of Azabismocines, Hexacoordinate Pentavalent Organobismuth Compounds

Autor: Minoura, Mao, Kanamori, Yuka, Miyake, Akira, Akiba, Kin-ya
Zdroj: Chemistry Letters; September 1999, Vol. 28 Issue: 9 p861-862, 2p
Abstrakt: Azabisomocine derivatives having a pentavalent bismuth and a nitrogen at 1,5-position were synthesized. The X-ray structural analysis reveals that these compounds have hexacoordinate distorted octahedral geometry which is caused by transannular bond formation between the bismuth and the nitrogen.
Databáze: Supplemental Index