Stereoselective Allylation of β-Hydroxy- and β-Amino-α,β-enones with Allyltrifluorosilane/Triethylamine Systems
| Autor: | Kira, Mitsuo, Sato, Kazuhiko, Sekimoto, Kazushi, Gewald, Rainer, Sakurai, Hideki |
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| Zdroj: | Chemistry Letters; April 1995, Vol. 24 Issue: 4 p281-282, 2p |
| Abstrakt: | Reactions of allyltrifluorosilanes with β-functional-α,β-enones such as o-hydroxy- and o-aminophenyl ketones and 1,3-diketones in the presence of triethylamine yielded the corresponding tertiary homoallyl alcohols in regiospecific and highly diastereoselective manner. |
| Databáze: | Supplemental Index |
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