Selective Synthesis of the Geometrical Isomers of O,O-Diethyl O-1-(N-methoxyimino)ethylphosphorothioate and a New Thiono-Thiolo Rearrangement Reaction
| Autor: | Sasaki, Mitsuru, Itoh, Yoshikazu, Yamamoto, Noboru, Yamada, Yoshimi |
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| Zdroj: | Chemistry Letters; November 1993, Vol. 22 Issue: 11 p1835-1838, 4p |
| Abstrakt: | Condensation of O,O-diethyl phosphorochloridothioate with N-methoxyacetamide in the presence of a base gave selectively the geometrical isomers of O,O-diethyl O-1-(N-methoxyimino)ethylphosphorothioate which on heating rearranged to the corresponding thiolo isomers having P–S–C=N linkage. |
| Databáze: | Supplemental Index |
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