Novel Conversion of Selenium-containing Five-membered Aromatics to Nitrogen-containing Six-membered Aromatics via Hetero Diels–Alder Reaction with Acetylenic Dienophiles

Autor: Takikawa, Yuji, Hikage, Shigeki, Matsuda, Youichi, Higashiyama, Kazuyuki, Takeishi, Yoshiyuki, Shimada, Kazuaki
Zdroj: Chemistry Letters; November 1991, Vol. 20 Issue: 11 p2043-2046, 4p
Abstrakt: Treatment of selenium-containing five-membered heteroaromatics with acetylenic dienophiles afforded several nitrogen heterocycles in good to moderate yields by using thermal reaction conditions. These reactions were thought to proceed through sequential [4+2] cycloaddition-selenium extrusion pathway.
Databáze: Supplemental Index