Autor: |
Tatehata, Akira, Mitani, Tsuyoshi |
Zdroj: |
Chemistry Letters; July 1989, Vol. 18 Issue: 7 p1167-1170, 4p |
Abstrakt: |
The stereoselectivities in the electron-transfer reactions of [Co(en)3]2+with eight ? anionic Co(III) complexes in aqueous solution have been determined by observing the enantiomeric excesses of the [Co(en)3]3+product. The results are compared with the ion-pairing stereoselectivity between [Co(en)3]3+and the anionic complexes. Even the ? anionic complexes which form favorable pairs with ?-[Co(en)3]3+yielded the excesses of ?-[Co(en)3]3+product. |
Databáze: |
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Externí odkaz: |
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