Autor: |
Maezawa, Akinori, Kane, Hiroshige, Okamoto, Yasuaki, Imanaka, Toshinobu |
Zdroj: |
Chemistry Letters; February 1988, Vol. 17 Issue: 2 p241-244, 4p |
Abstrakt: |
The thermal stabilities of Mo(CO)6and subcarbonyl species encaged in a zeolite were found to depend markedly on the Si/Al ratio and cation involved. A highly selective formation of cis-2-butene was observed for the hydrogenation of butadiene over the subcarbonyl species. These thermal and catalytic properties of the carbonyls are correlated to the basicity of the zeolite. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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