Thermal Stabilities and Catalytic Activities of Molybdenum Carbonyls Encapsulated in Zeolites

Autor: Maezawa, Akinori, Kane, Hiroshige, Okamoto, Yasuaki, Imanaka, Toshinobu
Zdroj: Chemistry Letters; February 1988, Vol. 17 Issue: 2 p241-244, 4p
Abstrakt: The thermal stabilities of Mo(CO)6and subcarbonyl species encaged in a zeolite were found to depend markedly on the Si/Al ratio and cation involved. A highly selective formation of cis-2-butene was observed for the hydrogenation of butadiene over the subcarbonyl species. These thermal and catalytic properties of the carbonyls are correlated to the basicity of the zeolite.
Databáze: Supplemental Index