The 1,1′-Trimethylenebis(pyridinyl) Diradical and Its Photosensitive Cyclomers

Autor: Muramatsu, Takashi, Hanaya, Kaoru, Onodera, Shinji, Ikegami, Yusaku
Zdroj: Chemistry Letters; August 1987, Vol. 16 Issue: 8 p1683-1686, 4p
Abstrakt: Reduction of 1,1′-trimethylenebis(pyridinium) dibromide with sodium amalgam produces the cyclomers of 1,1′-trimethylene-bis(pyridinyl) diradical. Meso and dl forms of the cyclomers are convertible to each other. Two conformations of the diradical are observed in the triplet ESR spectrum at 77 K.
Databáze: Supplemental Index