The 1,1′-Trimethylenebis(pyridinyl) Diradical and Its Photosensitive Cyclomers
Autor: | Muramatsu, Takashi, Hanaya, Kaoru, Onodera, Shinji, Ikegami, Yusaku |
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Zdroj: | Chemistry Letters; August 1987, Vol. 16 Issue: 8 p1683-1686, 4p |
Abstrakt: | Reduction of 1,1′-trimethylenebis(pyridinium) dibromide with sodium amalgam produces the cyclomers of 1,1′-trimethylene-bis(pyridinyl) diradical. Meso and dl forms of the cyclomers are convertible to each other. Two conformations of the diradical are observed in the triplet ESR spectrum at 77 K. |
Databáze: | Supplemental Index |
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