Autor: |
Goto, Yoshitaka, Sugita, Keijiro, Takahashi, Toru, Ohga, Yasushi, Asano, Tsutomu |
Zdroj: |
Chemistry Letters; July 2003, Vol. 32 Issue: 7 p618-619, 2p |
Abstrakt: |
It was experimentally demonstrated that microscopic friction between a reactant molecule and the surrounding solvent during a unimolecular structural change increased with increasing bulkiness of substituents and it is suggested that this dependence can be used to identify a moving molecular moiety in the reactant inside of a solvation shell. |
Databáze: |
Supplemental Index |
Externí odkaz: |
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