An Experimental Attempt to Identify a Moving Molecular Moiety in a Solvent Matrix

Autor: Goto, Yoshitaka, Sugita, Keijiro, Takahashi, Toru, Ohga, Yasushi, Asano, Tsutomu
Zdroj: Chemistry Letters; July 2003, Vol. 32 Issue: 7 p618-619, 2p
Abstrakt: It was experimentally demonstrated that microscopic friction between a reactant molecule and the surrounding solvent during a unimolecular structural change increased with increasing bulkiness of substituents and it is suggested that this dependence can be used to identify a moving molecular moiety in the reactant inside of a solvation shell.
Databáze: Supplemental Index