The Benzylation and Phenylation Reactions of Unsaturated Compounds Using Organo Monohalides and Polynuclear Iron Carbonyl

Autor: Rhee, Ilsong, Mizuta, Norio, Ryang, Membo, Tsutsumi, Shigeru
Zdroj: Bulletin of the Chemical Society of Japan; June 1968, Vol. 41 Issue: 6 p1417-1422, 6p
Abstrakt: The reaction of iodobenzene and benzyl halides (Cl, Br and I) with Fe3(CO)12(mole ratio; Fe3(CO)12/R–X=1/3) gave the corresponding symmetrical ketones (18–55.2%). The increasing order of the reactivity of the organo halides to Fe3(CO)12was as follows: iodobenzene
Databáze: Supplemental Index