| Autor: |
Kato, Tadashi, Fujiyama, Tsunetake, Nomura, Hiroyasu |
| Zdroj: |
Bulletin of the Chemical Society of Japan; November 1982, Vol. 55 Issue: 11 p3368-3372, 5p |
| Abstrakt: |
A concentration fluctuation value obtained from Rayleigh scattering intensity was confirmed to give a thermodynamic quantity of an equilibrium system. An observation of concentration fluctuation by a light scattering method was found to be the most direct and useful way of determining a concentration derivative of a chemical potential. For methanol, ethanol, and 1-propanol–carbon tetrachloride systems, the Kirkwood-Buff parameters, G11, G22, and G12, were determined by the use of concentration fluctuation data. The structure of these systems was discussed on the basis of the calculated Kirkwood-Buff parameters. |
| Databáze: |
Supplemental Index |
| Externí odkaz: |
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