The Synthesis and Studies of Several [2.2.2]Ferrocenophane Derivatives

Autor: Kasahara, Akira, Izumi, Taeko, Shimizu, Iwao, Oikawa, Tadashi, Umezawa, Hiroshi, Hoshino, Isao
Zdroj: Bulletin of the Chemical Society of Japan; April 1983, Vol. 56 Issue: 4 p1143-1148, 6p
Abstrakt: Several ferrocenophanes, in which the two cyclopentadienyl rings are linked by acetylenic and olefinic bonds and aromatic rings, have been synthesized viathe titanium-induced reductive coupling of the corresponding formyl compounds. The structures of these ferrocenophane compounds were determined by means of their IR and NMR spectra. The transannular π-electronic interactions between the two chromophores were examined on the basis of the electronic spectra.
Databáze: Supplemental Index