Substituent Effects on Photochemical Extrusion of Phosphorus Group from 3-Phospholene System

Autor: Tomioka, Hideo, Nakamura, Shigehiro, Ohi, Tsutomu, Izawa, Yasuji
Zdroj: Bulletin of the Chemical Society of Japan; December 1976, Vol. 49 Issue: 12 p3707-3708, 2p
Abstrakt: The rate of photo-extrusion of phenylphosphinidene oxide from 1-phenyl-3-phospholene 1-oxide was enhanced by ß-methylation. It was found that the photoextrusion can be extended to the generation of phenylphosphinidene, but attempts to generate other phosphorus intermediates i.e., metaphosphite and methylphosphinidene oxide, were unsuccessful.
Databáze: Supplemental Index