Unusual Concentration–Rate Profiles for Oxidation of a Pair of Associating Thiols

Autor: Kato, Jun-ichi, Ito, Masato M, Hagino, Kazuomi, Naitoh, Narumi, Misaka, Makoto, Fujishiro, Einosuke, Endo, Tadashi
Zdroj: Bulletin of the Chemical Society of Japan; April 1988, Vol. 61 Issue: 4 p1419-1421, 3p
Abstrakt: In base-catalyzed oxidation of a pair of associating thiols [HSCH2–CONHCONH–Ph and HSCH2CH2NHCONHCO–C6H13] with oxygen, there are concentration regions where initial rates decrease with increasing concentrations of the thiols. For a pair of nonassociating thiols [HSCH2CO2C2H5and HSCH2CH2OH], initial rates increase linearly with concentrations of the thiols.
Databáze: Supplemental Index